مروری بر پلی یورتان های پایه آبی
الموضوعات : زیست پلاستیک ها و پلیمرهای تجديد پذیر
1 - تهران
الکلمات المفتاحية: پلی یورتان های پایه آبی حلال چسب و روکش,
ملخص المقالة :
پلي يورتان هاي پايه آبي از لحاظ علمي، تجاري و صنعتي مورد توجه هستند. امروزه کاربرد حلال های آلی به دليل اشتعال پذیری و همچنین حساسيت بستر نسبت به آن ها، محدود شده است. به دلیل قيمت زياد حلال هاي آلي از طرفی و يكفيتد بسيار خوب پلي يورتا نهاي پايه آبي از سوی دیگر و همچنین با توجه به ملاحظات زيست محيطي دركاهش نشر حلال به اتمسفر، پلي يورتان هاي پايه آبي، جایگزین مناسبی برای حلال های آلی هستند. پلي يورتان هاي پايه آبي شامل مقدار بسيار اندك يا عاری از حلال، غيرسمي و غيرقابل اشتعالند و قابليت كاربرد در چسب و روكش ها را دارند و در دماي محيط تشكیل فيلم مي دهند. به علاوه، چسبندگي عالي به سطوح مختلف از جمله شيشه و الياف پليمري، انعطاف پذيري، خواص رئولوژيکی مطلوب و گرانروي كم در وزن مولكولي زياد از ديگر ویژگی های آن ها است. در این مقاله، روش های سنتزپلی یورتان های پایه آبی مورد بررسی قرار گرفته است.
المصادر:
1. Nelson A. M., Long T. E., “Synthesis, Properties, and Applications of Ion-containing Polyurethane Segmented Copolymers”, Macromol. Chem. Phys., 215, 2161-2174, 2014.
2. Guo Y. H., Guo J. J., Li S. C., Li X., Wang G. S., Huang Z., “Properties and Paper Sizing Application of Waterborne Polyurethane Emulsions Synthesized with TDI and IPDI”, Colloids Surf. A: Physicochem. Eng. Asp., 427, 53-61, 2013.
3. Fang C., Zhou X., Yu Q., Liu S., Guo D., “Synthesis and Characterization of Low Crystalline Waterborne Polyurethane for Potential Application in Water-based ink Binder”, Prog. Org. Coat., 77, 61-71, 2014.
4.Poussard L., Lazko J., Mariage J., Raquez J. M., Dubois P., “Biobased Waterborne Polyurethanes for Coating Applications: How Fully Biobased Polyols May Improve the Coating Properties”,Prog. Org. Coat., 97, 175-183, 2016.
5. Zhang S., Chen Z., Guo M., Bai H., Liu X., “Synthesis and Characterization of Waterborne UV-curable Polyurethane Modified with Side-chain Triethoxysilane and Colloidal Silica”, Colloids Surf. A: Physicochem. Eng. Asp., 468, 1-9, 2015.
6. Liu N., Zhao Y., Kang M., Wang J., Wang X., Feng Y., Yin N., Li Q., “The Effects of the Molecular Weight and Structure of Polycarbonatediols on the Properties of Waterborne Polyurethanes”, Prog. Org. Coat., 82, 46-56, 2015.
7. Jaudouin O., Robin J. J., Lopez-Cuesta J. M., Perrin D., Imbert C., “Ionomer-based Polyurethanes: a Comparative Study of Properties and Applications”, Polym. Int., 61, 495-510, 2012.
8. Garcia- Pacios V., Jofre-Reche J. A., Costa, V., Colera M., Martin-Martinez J. M., “Coatings Prepared from Waterborne Polyurethane Dispersions Obtained with Polycarbonates of 1,6-Hexanediol of Different Molecular Weights”, Prog. Org. Coat., 76, 1484-1493, 2013.
9. Chen, H., Chen D., Fan Q., Yu X., “Synthesis and Properties of Polyurethane Ionomers Based on Carboxylated Polycaprolactone”, J. Appl. Polym. Sci.,76, 2049-2056, 2000.
10. Honarkar M., Barikani M., “Nanoclay Dispersion and its Effect on Properties of Waterborne Polyurethanes”, Iran. J. Polym. Sci. Technol., 26, 393-401, 2013.
11. Honarkar M., Barmar M., Barikani M., “New Sulfonated Waterborne Polyurethane Dispersions: Preparation and Characterization”, J. Disper. Sci. Technol., 37, 1219-1225, 2016.
12.Honarkar H., Barmar M., Barikani M., Shokrollahi P., “Synthesis and Characterization of Polyhedral Oligomeric Silsesquioxane-based Waterborne Polyurethane Nanocomposites”, Korean J. Chem. Eng., 33, 319-329, 2016.
13. Szycher M., Szycher's Handbook of Polyurethanes, 2 nd ed., CRC Press, USA, 2013.
14. Honarkar M., Barmar M., Barikani M., “Synthesis, Characterization and Properties of Waterborne Polyurethanes Based on Two Different Ionic Centers”, Fibers Polym., 16, 718-725, 2015.
15.Zhou X., Li Y., Fang C., Li S., Cheng Y., Lei W., Meng X., “Recent Advances in Synthesis of Waterborne Polyurethane and Their Application in Water-based ink: A Review”, J. Mater. Sci. Technol., 31, 708-722, 2015.
16. Ramesh S., Tharanikkarasu K., Mahesh G. N., Radhakrishnan G., “Synthesis, Physicochemical Characterization, and Applications of Polyurethane Ionomers: A Review”, J.Macromol. Sci., Part C: Polym. Rev., 38, 481-509,1998.
17. Barikani M., Honarkar H., Barikani Me., “Synthesis and Characterization of Chitosan-based Polyurethane Elastomer Dispersions”,Monatsh. Chem.,141, 653-659, 2010.
18. Manvi G. N., Jagtap R. N., “Effect of DMPA Content of Polyurethane Dispersion on Coating Properties”, J. Disper. Sci. Technol., 31, 1376-1382, 2010.
19. Mishra A. K., Mishra R. S., Narayan R., Raju K. V. S. N., “Effect of Nano ZnO on the Phase Mixing of Polyurethane Hybrid Dispersions”, Prog. Org. Coat., 67, 405-413, 2010.
20. Cakic S. M., Spirkova M., Ristic I. S., B-Simendic J. K., M-Cincovic M., Poreba R., “The Waterborne Polyurethane Dispersions Based on Polycarbonate Diol: Effect of Ionic Content”, Mater. Chem. Phys., 138, 277-285, 2013.
21.Lee D. K., Tsai H. B., Yang Z. D., Tsai R. S., “Polyurethane Dispersions Derived from Polycarbonatediols by a Solvent-free Process”, J. Appl. Polym. Sci., 126, E275-E282, 2012.
22. Lei L., Xia Z., Cao G., Zhong L.,“Synthesis and Adhesion Property of Waterborne Polyurethanes with Different Ionic Group Contents”, ColloidPolym. Sci., 292, 527-532,2014.
23.Shin M., Lee Y., Rahman M., Kim H., “Synthesis and Properties of Waterborne Fluorinated Polyurethane-acrylate Using a Solvent-/Emulsifier-free Method”, Polymer, 54, 4873-4882, 2013.
24. Fang Z., Zhou M., Zhong J., Qi Y., Li L., Dong Q., “Preparation and Properties of Novel Ultraviolet-cured Waterborne Polyurethanes”, High Perform. Polym., 25, 668-676, 2013.
25. Wang L, Yang B, Wang X. L., Tang X. Z., “A Novel Polymer Electrolyte Based on Polydioxolane Polyurethane with Na+ Single-ionic Conductivity” , J. Appl. Polym. Sci., 71, 1711-1719, 1999.
26. Robila G., Buruiana T., Buruiana E. C., “Synthesis and Properties of Some Polyurethane Anionomers with Carboxylate Groups”, Eur. Polym. J., 35, 1305-1311,1999.
27. Charnetskaya A. G., Polizos G., Shtompel V. I., Privalko E. G., Kercha Y. Y., Pissis P.,“Phase Morphology and Molecular Dynamics of a Polyurethane Ionomer Reinforced with a Liquid Crystalline Filler”, Eur. Polym. J., 39, 2167-2174,2003.
28. Buruiana E. C., Buruiana T., Strat G., Strat M.,“Synthesis and Optical Properties of New Polyurethane Cationomers with Anchored Stilbene Chromophores”, J. Polym. Sci. A: Polym.Chem., 40, 1918-1928, 2002.
29. Wu G. H., Hsu S. H., “Synthesis of Water-based Cationic Polyurethane for Antibacterial and Gene Delivery Applications”, Colloids Surf. B: Biointerfaces., 146, 825-832, 2016.
30. Chen F., Hehl J., Su Y., Mattheis C., Greiner A., Agarwal S., “Smart Secondary Polyurethane Dispersions”,Polym. Int., 62, 1750-1757, 2013.
31. Zhang M., Hemp S. T., Zhang M., Allen M. H., Carmean Jr. R. N., Moore R. B., Long T. E., “Water-dispersible Cationic Polyurethanes Containing Pendant Trialkylphosphoniums”, Polym. Chem., 5, 3795-3803, 2014.
32.Garrison T. F., Zhang Z., Kim H. J., Mitra D., Xia Y., Pfister D. P., Brehm-Stecher B. F., Larock R. C., Kessler M. R., “Thermo-mechanical and Antibacterial Properties of Soybean Oil-Based Cationic Polyurethane Coatings: Effect of Amine Ratio and Degree of Crosslinking”, Macromol. Mater. Eng., 299, 1042-1051, 2014.
33.Gao R., Zhang M., Wang S. W., Moore R. B., Colby R. H., Long T. E., “Polyurethanes Containing an Imidazolium Diol-based Ionic-liquid Chain Extender for Incorporation of Ionic-Liquid Electrolytes”, Macromol. Chem. Phys., 214, 1027-1036, 2013.
34. Krol P., Krol B., Stagraczynski R., Skrzypiec K., “Waterborne Cationomer Polyurethane Coatings with Improved Hydrophobic Properties”, J. Appl. Polym. Sci., 127, 2508-2519, 2013.
35.Lu X., Wang Y., Wu X., “Investigation of Interaction of Polyester-polyurethanes and Their Zwitterionomers by Solid-state Nuclear Magnetic Resonance”, Polymer, 33, 958-962, 1992.
36.Cao J., Chen Y. W., Wang X., Luo X. L., “Enhancing Blood Compatibility of Bio Degradable Polymers by Introducing Sulfobetaine”,J. Biomed. Mater. Res., Part A, 97A, 472-479, 2011.
37. Cao J., Yang M., Lu A., Zhai S., Chen Y., Luo X., “Polyurethanes Containing Zwitterionic Sulfobetaines and Their Molecular Chain Rearrangement in Water”, J. Biomed. Mater. Res., Part A, 101A, 909-918, 2013.
38. Cakic S. M., Stamenkovic J. V., Djordjevic D. M., Ristic I. S., “Synthesis and Degradation Profile of Cast Films of PPG-DMPA-IPDI Aqueous Polyurethane Dispersions Based on Selective Catalyst”, Polym. Deg. Stab., 94, 2015-2022, 2009.
39. Saetung A., Kaenhin L., Klinpituksa P., Rungvichaniwat A., Tulyapitak T., Munleh S., Campistron I., Pilard J. F., “Synthesis, Characteristic, and Properties of Waterborne Polyurethane Based on Natural Rubber”, J. Appl. Polym, Sci., 124,2742-2752, 2012.
40. Hu X., Zhang X., Liu J., Dai J., “Synthesis, Characterization and Fluorescence Performance of a Waterborne Polyurethane-based Fluorescent Dye 4-amino-N-cyclohexyl-1,8-naphthalimide, WPU-ACN”, Polym. Int., 63, 453-458, 2014.
41. Nanda A. K., Wicks D. A., “The Influence of the Ionic Concentration of the Polymer, Degree of Neutralization and Chain Extension on Aqueous Polyurethane Dispersions Prepared by the Acetone Process”, Polymer, 47, 1805-1811, 2006.
42. Sardon H., Irusta L., Fernandez-Berridi M. J., Luna J., LansalotM., Bourgeat-Lami E., “Waterborne Polyurethane Dispersions Obtained by the Acetone Process: A Study of Colloidal Features ”, J. Appl. Polym, Sci., 120, 2054-2062, 2011.
43. Jhon Y. K., Cheong I. W., Kim J. H., “Chain Extension Study of Aqueous Polyurethane Dispersions”, Colloids Surf. A: Physicochem. Eng. Asp., 179, 71-78, 2001.
44. Li Q. A., Sun D. C., “Synthesis and Characterization of High Solid Content Aqueous Polyurethane Dispersion”, J. Appl. Polym. Sci., 105, 2516-2524, 2007.
45. Nasrullah M. J., Bahr J. A., Gallagher-Lein C., Webster D. C., Roesler R. R., Schmitt P., “Automated Parallel Polyurethane Dispersion Synthesis and Characterization”, J. Coat. Technol.Res., 6, 1-10, 2009.
1. Nelson A. M., Long T. E., “Synthesis, Properties, and Applications of Ion-containing Polyurethane Segmented Copolymers”, Macromol. Chem. Phys., 215, 2161-2174, 2014.
2. Guo Y. H., Guo J. J., Li S. C., Li X., Wang G. S., Huang Z., “Properties and Paper Sizing Application of Waterborne Polyurethane Emulsions Synthesized with TDI and IPDI”, Colloids Surf. A: Physicochem. Eng. Asp., 427, 53-61, 2013.
3. Fang C., Zhou X., Yu Q., Liu S., Guo D., “Synthesis and Characterization of Low Crystalline Waterborne Polyurethane for Potential Application in Water-based ink Binder”, Prog. Org. Coat., 77, 61-71, 2014.
4.Poussard L., Lazko J., Mariage J., Raquez J. M., Dubois P., “Biobased Waterborne Polyurethanes for Coating Applications: How Fully Biobased Polyols May Improve the Coating Properties”,Prog. Org. Coat., 97, 175-183, 2016.
5. Zhang S., Chen Z., Guo M., Bai H., Liu X., “Synthesis and Characterization of Waterborne UV-curable Polyurethane Modified with Side-chain Triethoxysilane and Colloidal Silica”, Colloids Surf. A: Physicochem. Eng. Asp., 468, 1-9, 2015.
6. Liu N., Zhao Y., Kang M., Wang J., Wang X., Feng Y., Yin N., Li Q., “The Effects of the Molecular Weight and Structure of Polycarbonatediols on the Properties of Waterborne Polyurethanes”, Prog. Org. Coat., 82, 46-56, 2015.
7. Jaudouin O., Robin J. J., Lopez-Cuesta J. M., Perrin D., Imbert C., “Ionomer-based Polyurethanes: a Comparative Study of Properties and Applications”, Polym. Int., 61, 495-510, 2012.
8. Garcia- Pacios V., Jofre-Reche J. A., Costa, V., Colera M., Martin-Martinez J. M., “Coatings Prepared from Waterborne Polyurethane Dispersions Obtained with Polycarbonates of 1,6-Hexanediol of Different Molecular Weights”, Prog. Org. Coat., 76, 1484-1493, 2013.
9. Chen, H., Chen D., Fan Q., Yu X., “Synthesis and Properties of Polyurethane Ionomers Based on Carboxylated Polycaprolactone”, J. Appl. Polym. Sci.,76, 2049-2056, 2000.
10. Honarkar M., Barikani M., “Nanoclay Dispersion and its Effect on Properties of Waterborne Polyurethanes”, Iran. J. Polym. Sci. Technol., 26, 393-401, 2013.
11. Honarkar M., Barmar M., Barikani M., “New Sulfonated Waterborne Polyurethane Dispersions: Preparation and Characterization”, J. Disper. Sci. Technol., 37, 1219-1225, 2016.
12.Honarkar H., Barmar M., Barikani M., Shokrollahi P., “Synthesis and Characterization of Polyhedral Oligomeric Silsesquioxane-based Waterborne Polyurethane Nanocomposites”, Korean J. Chem. Eng., 33, 319-329, 2016.
13. Szycher M., Szycher's Handbook of Polyurethanes, 2 nd ed., CRC Press, USA, 2013.
14. Honarkar M., Barmar M., Barikani M., “Synthesis, Characterization and Properties of Waterborne Polyurethanes Based on Two Different Ionic Centers”, Fibers Polym., 16, 718-725, 2015.
15.Zhou X., Li Y., Fang C., Li S., Cheng Y., Lei W., Meng X., “Recent Advances in Synthesis of Waterborne Polyurethane and Their Application in Water-based ink: A Review”, J. Mater. Sci. Technol., 31, 708-722, 2015.
16. Ramesh S., Tharanikkarasu K., Mahesh G. N., Radhakrishnan G., “Synthesis, Physicochemical Characterization, and Applications of Polyurethane Ionomers: A Review”, J.Macromol. Sci., Part C: Polym. Rev., 38, 481-509,1998.
17. Barikani M., Honarkar H., Barikani Me., “Synthesis and Characterization of Chitosan-based Polyurethane Elastomer Dispersions”,Monatsh. Chem.,141, 653-659, 2010.
18. Manvi G. N., Jagtap R. N., “Effect of DMPA Content of Polyurethane Dispersion on Coating Properties”, J. Disper. Sci. Technol., 31, 1376-1382, 2010.
19. Mishra A. K., Mishra R. S., Narayan R., Raju K. V. S. N., “Effect of Nano ZnO on the Phase Mixing of Polyurethane Hybrid Dispersions”, Prog. Org. Coat., 67, 405-413, 2010.
20. Cakic S. M., Spirkova M., Ristic I. S., B-Simendic J. K., M-Cincovic M., Poreba R., “The Waterborne Polyurethane Dispersions Based on Polycarbonate Diol: Effect of Ionic Content”, Mater. Chem. Phys., 138, 277-285, 2013.
21.Lee D. K., Tsai H. B., Yang Z. D., Tsai R. S., “Polyurethane Dispersions Derived from Polycarbonatediols by a Solvent-free Process”, J. Appl. Polym. Sci., 126, E275-E282, 2012.
22. Lei L., Xia Z., Cao G., Zhong L.,“Synthesis and Adhesion Property of Waterborne Polyurethanes with Different Ionic Group Contents”, ColloidPolym. Sci., 292, 527-532,2014.
23.Shin M., Lee Y., Rahman M., Kim H., “Synthesis and Properties of Waterborne Fluorinated Polyurethane-acrylate Using a Solvent-/Emulsifier-free Method”, Polymer, 54, 4873-4882, 2013.
24. Fang Z., Zhou M., Zhong J., Qi Y., Li L., Dong Q., “Preparation and Properties of Novel Ultraviolet-cured Waterborne Polyurethanes”, High Perform. Polym., 25, 668-676, 2013.
25. Wang L, Yang B, Wang X. L., Tang X. Z., “A Novel Polymer Electrolyte Based on Polydioxolane Polyurethane with Na+ Single-ionic Conductivity” , J. Appl. Polym. Sci., 71, 1711-1719, 1999.
26. Robila G., Buruiana T., Buruiana E. C., “Synthesis and Properties of Some Polyurethane Anionomers with Carboxylate Groups”, Eur. Polym. J., 35, 1305-1311,1999.
27. Charnetskaya A. G., Polizos G., Shtompel V. I., Privalko E. G., Kercha Y. Y., Pissis P.,“Phase Morphology and Molecular Dynamics of a Polyurethane Ionomer Reinforced with a Liquid Crystalline Filler”, Eur. Polym. J., 39, 2167-2174,2003.
28. Buruiana E. C., Buruiana T., Strat G., Strat M.,“Synthesis and Optical Properties of New Polyurethane Cationomers with Anchored Stilbene Chromophores”, J. Polym. Sci. A: Polym.Chem., 40, 1918-1928, 2002.
29. Wu G. H., Hsu S. H., “Synthesis of Water-based Cationic Polyurethane for Antibacterial and Gene Delivery Applications”, Colloids Surf. B: Biointerfaces., 146, 825-832, 2016.
30. Chen F., Hehl J., Su Y., Mattheis C., Greiner A., Agarwal S., “Smart Secondary Polyurethane Dispersions”,Polym. Int., 62, 1750-1757, 2013.
31. Zhang M., Hemp S. T., Zhang M., Allen M. H., Carmean Jr. R. N., Moore R. B., Long T. E., “Water-dispersible Cationic Polyurethanes Containing Pendant Trialkylphosphoniums”, Polym. Chem., 5, 3795-3803, 2014.
32.Garrison T. F., Zhang Z., Kim H. J., Mitra D., Xia Y., Pfister D. P., Brehm-Stecher B. F., Larock R. C., Kessler M. R., “Thermo-mechanical and Antibacterial Properties of Soybean Oil-Based Cationic Polyurethane Coatings: Effect of Amine Ratio and Degree of Crosslinking”, Macromol. Mater. Eng., 299, 1042-1051, 2014.
33.Gao R., Zhang M., Wang S. W., Moore R. B., Colby R. H., Long T. E., “Polyurethanes Containing an Imidazolium Diol-based Ionic-liquid Chain Extender for Incorporation of Ionic-Liquid Electrolytes”, Macromol. Chem. Phys., 214, 1027-1036, 2013.
34. Krol P., Krol B., Stagraczynski R., Skrzypiec K., “Waterborne Cationomer Polyurethane Coatings with Improved Hydrophobic Properties”, J. Appl. Polym. Sci., 127, 2508-2519, 2013.
35.Lu X., Wang Y., Wu X., “Investigation of Interaction of Polyester-polyurethanes and Their Zwitterionomers by Solid-state Nuclear Magnetic Resonance”, Polymer, 33, 958-962, 1992.
36.Cao J., Chen Y. W., Wang X., Luo X. L., “Enhancing Blood Compatibility of Bio Degradable Polymers by Introducing Sulfobetaine”,J. Biomed. Mater. Res., Part A, 97A, 472-479, 2011.
37. Cao J., Yang M., Lu A., Zhai S., Chen Y., Luo X., “Polyurethanes Containing Zwitterionic Sulfobetaines and Their Molecular Chain Rearrangement in Water”, J. Biomed. Mater. Res., Part A, 101A, 909-918, 2013.
38. Cakic S. M., Stamenkovic J. V., Djordjevic D. M., Ristic I. S., “Synthesis and Degradation Profile of Cast Films of PPG-DMPA-IPDI Aqueous Polyurethane Dispersions Based on Selective Catalyst”, Polym. Deg. Stab., 94, 2015-2022, 2009.
39. Saetung A., Kaenhin L., Klinpituksa P., Rungvichaniwat A., Tulyapitak T., Munleh S., Campistron I., Pilard J. F., “Synthesis, Characteristic, and Properties of Waterborne Polyurethane Based on Natural Rubber”, J. Appl. Polym, Sci., 124,2742-2752, 2012.
40. Hu X., Zhang X., Liu J., Dai J., “Synthesis, Characterization and Fluorescence Performance of a Waterborne Polyurethane-based Fluorescent Dye 4-amino-N-cyclohexyl-1,8-naphthalimide, WPU-ACN”, Polym. Int., 63, 453-458, 2014.
41. Nanda A. K., Wicks D. A., “The Influence of the Ionic Concentration of the Polymer, Degree of Neutralization and Chain Extension on Aqueous Polyurethane Dispersions Prepared by the Acetone Process”, Polymer, 47, 1805-1811, 2006.
42. Sardon H., Irusta L., Fernandez-Berridi M. J., Luna J., LansalotM., Bourgeat-Lami E., “Waterborne Polyurethane Dispersions Obtained by the Acetone Process: A Study of Colloidal Features ”, J. Appl. Polym, Sci., 120, 2054-2062, 2011.
43. Jhon Y. K., Cheong I. W., Kim J. H., “Chain Extension Study of Aqueous Polyurethane Dispersions”, Colloids Surf. A: Physicochem. Eng. Asp., 179, 71-78, 2001.
44. Li Q. A., Sun D. C., “Synthesis and Characterization of High Solid Content Aqueous Polyurethane Dispersion”, J. Appl. Polym. Sci., 105, 2516-2524, 2007.
45. Nasrullah M. J., Bahr J. A., Gallagher-Lein C., Webster D. C., Roesler R. R., Schmitt P., “Automated Parallel Polyurethane Dispersion Synthesis and Characterization”, J. Coat. Technol.Res., 6, 1-10, 2009.
