اهميت مطالعات ژئوشيمي سطحي در اکتشافات ذخاير هيدروکربني: با ذکر مطالعه موردي در استان خوزستان، جنوب غرب ايران
الموضوعات : زمین شناسی نفتزینب علیزاده 1 , بهمن سلیمانی 2 , بهزاد خانی 3
1 - گروه زمین شناسی نفت و حوضه¬های رسوبی، دانشگاه شهید چمران اهواز، اهواز
2 - استاد گروه زمين شناسي نفت و حوضه¬هاي رسوبي، دانشگاه شهيد چمران اهواز، اهواز، ايران
3 - مدیر فنی شرکت انرژی پژوهان آریانا، اهواز
الکلمات المفتاحية: ژئوشیمی سطحی, ریزنشت, فروافتادگی دزفول, آنالیز میکروبی, گاز خاک جذب شده,
ملخص المقالة :
مطالعات ژئوشيمي سطحي از ابزارهاي مهم در تمام مراحل اکتشاف پتانسيل هيدروکربني از شناسايي حوضه پيشاني (فورلند) تا اکتشاف دقيق، و چشمانداز بر اساس شار احتمالي هيدروکربنها، شناسايي زونهاي فرعي در ميادين بالغ، نظارت بر زهکشي هيدروکربنهاي مرتبط با توليد در طول زمان بشمار مي رود. در مطالعه کنوني، پيش بيني پتانسيل هيدروکربني ناحيهاي در شمال شرق خوزستان (جنوب شرق فروافتادگي دزفول) با استفاده از آناليز گاز خاک نمونه هاي جمع آوري شده (تعداد 62 نمونه) انجام شده است. سنجش مقادير گازخاک با استفاده از روشهاي استخراج اسيد (AE) و بررسي ميکروبي و استخراج ژن آنها (MT1-MT2) است. تحليل دادهها نشان داد که تغييرات پارامترهاي آناليز MT2 در امتداد خطوط نمونه برداري در نمودارهاي هيستوگرامي کج شدگي مثبت را بواسطه وجود آنومالي ژئوشيمي سطحي و حضور هيدروکربن در مخازن احتمالي نشان ميدهد. نسبتهاي اتان در مقابل متان، اتان در مقابل پروپان و c1/c2+c3 در مقابل c2/c3+c4 نشان دهنده نوع هيدروکربن به دام افتاده در مخازن زير زميني مي باشند. بر اساس دادههاي حاصل، نمونههاي محدوده مطالعاتي در محدوده مخازن نفتي و در مواردي مخازن نفتي همراه با گاز قرار ميگيرند. مخازن هيدرروکربني براساس نسبت استاندارد c3/c1×1000، با دارا بودن محدوده 20-200، تجمع هيدروکربني با اکثريت هيدروکربن هاي مايع و در مواردي همراه با گاز را نشان ميدهند. براساس logc1/(c2+c3) در مقابل logc2/(c3+c4) نيز نشان دهنده غالب بودن هيدرروکربن مايع و در موارد کمتري هيدروکربنهاي گازي همراه با نفت ميباشد. تغييرات داده هاي پارامترهاي آناليز MT1 در امتداد خطوط نمونه برداري نيز حاکيي از وجود انطباق خوب ميان آنومالي بالاي اين پارامترها با عوارض ساختاري زمين شناسي زيرسطحي (گسل) است. نتايج کنوني نشانه غالب بودن نمونهها در محدوده هيدروکربن هاي مايع و در مواردي همراه با کلاهک گازي است. هرچند تعداد معدودي از نمونه ها خصوصيات هيدروکربني با مشخصات نفت سنگين و همچنين آلودگيهاي سطحي را نشان ميدهند. بطورکلي نتايج تمامي روشهاي مورد استفاده در پيش بيني آنومالي گاز خاک تطابق خوبي را با عناصر ساختاري ناحيه نشان داده، لذا ابزار مفيدي براي شناسايي و رصد گسلهاي پنهان در سطح ميتواند محسوب گردد.
[1]ABRAMS, M., 2005, Significance of hydrocarbon seepage relative to petroleum generation and entrapment. Mar Pet Geol., 22:457–477
[2]AL-SHAIB, Z., CAIRNS, J., and PUCKETTE, J., 1994, Hydrocarbon-induced diagenetic aureoles (HIDA): Indicators of deeper, leaky reservoirs. APGE Bulletin, 10, 24-48.
[3]AMINZADEH, F., BERGE, T., and CONNOLLY, D., 2013, Hydrocarbon Seepage from Source to Surface: Geophysical Developments Series No. 16, publ. jointly by AAPG and SEG, 253 p.
[4]ARMSTRONG, F.E., and HEEMSTRA, R, J., 1973: Radiation halos and hydrocarbon reservoirs, a review. US Bureau of Mines, Information Circular 8579.
[5]ASADZADEH, S., & DE SOUZA FILHO, C. R., 2019. Characterization of microseepage-induced diagenetic changes in the Upper-Red Formation, Qom region, Iran. Part I: Outcrop, geochemical, and remote sensing studies. Marine and Petroleum Geology, 104149. doi:10.1016/j.marpetgeo.2019.1041
[6]ASADZADEH, S., and DE SOUZA FILHO, C.R., 2017, Spectral remote sensing for onshore seepage characterization; a critical overview. Earth Sci Rev., 168:48–72.
[7]BAUM, M., SCHMITT, M., WAGNER, M., WESTERLAGE, C., 2008, Geochemicaland microbiological surface investigation in northern Germanyindicates interesting hydrocarbon potential. Oil Gas Euro Magaz 34(1):10. https:// www. scopus.com/ record/ display.uri? eid=2- s2.0-41149 15090 8& origin= inward
[8]BELL, H., CAMILLONE, N., ABRAM, K., ANN BRUNS, M., YERGEAU, E., ST-ARNAUD, M., 2021, Hydrocarbon substrate richness impacts microbial abundance, microbiome composition, and hydrocarbon loss Terrence. Applied Soil Ecology, 165, 104015 https://doi.org/10.1016/j.apsoil.2021.104015.
[9]BERNARD, B.B., BROOKS, J.M., SACKETT, W.M., 1978, Light hydrocarbons in recent Texas continental shelf and slope sediments. J. Geophys. Res. Oceans, 83 (C8), 4053-4061.
[10]BHUYAN, S., PHUKAN, A., YADAV, M., JYOTI GIRI, S., BEGUM, S., DAS, S., KABYASHREE, K., PRIYADARSHANI, P., SARKAR, S., JAYSWAL, A., KUMAR, A., MANDAL, M., KUMAR RAY, S., 2023, Microliter spotting and micro-colony observation: A rapid and simple approach for counting bacterial colony forming units. Journal of Microbiological Methods, 207, 106707. https://doi.org/10.1016/j.mimet.2023.106707.
[11] Blankinship, L.A., 2022, BI302 Clinical Microbiology Lab Manual. North Alabama Digital Press at Collier Library, 80p.
[12] BOYLE, R.W., and GARRETT, R.G., 1970. Geochemical prospecting - a review of its status and future. Earth-Sci. Rev., 6: 51--75.
[13]BRAY, E.E., 1956a. Geochemical exploration methods. U.S. Pat., 2,742,575.
[14]BRAY, E.E., 1956b. Method of geochemical prospecting. U.S. Pat., 2,773,991.
[15]CHEN, S., ZHAO, Y., ZHAO, L., LIU, Y., ZHOU, C., 2017. Hydrocarbon microseepage detection by altered minerals mapping from airborne hyper-spectral data in Xifeng Oilield, China. J Earth Sci 28:656–665. https://doi.org/10.1007/s12583-015-0604-1.
[16]CHILINGAR, G.V., and KARIM, M., 1962. Gaseous survey methods in exploration and prospecting for oil and gas: a review. Alberta Soc. Pet. Geol. J., 10: 610--617.
[17]CLARK, J.R., RENO, N.V., TOMPKINS, R., 2003. Mapping of reservoirs and subsurface structures using selective analysis of the surface chemistry of soil particles. 88th Annual Meeting of AAPG (Extended Abstract), Salt Lake City, May 11-14.
[18]CLARKE, R.H., and CLEVERLY, R.W., 1991. Petroleum seepage and postaccumulation migration. Geol Soc Lond Spec Publ 59(1):265–271.
[19]COLLINS, A.G., 1975, Chapter 10. Geochemical Methods of Exploration for Petroleum and Natural Gas. (1975). In: Geochemistry of Oilfield Waters, 307–341. http/doi:10.1016/s0376-7361(08)70203-6.
[20]COOPER, M., 2007. Structural style and hydrocarbon prospectivity in fold and thrust belts: a global review. In: RIES, A. C., BUTLER, R. W. H. & GRAHAM, R. H. (eds) Deformation of the Continental Crust: The Legacy of Mike Coward. Geological Society [London] Special Publication, 272, 447–472.
[21]COSTANZO-ÁLVAREZ, V., MENDOZA, J., ALDANA, M., JACOME, M., DÍAZ, M., RAMIREZ, K., and AMON, C.H., 2022. Comparing direct numerical modeling predictions with field evidence for methane vertical microseepage in two geological settings. Front. Earth Sci. 10:940799. http/doi: 10.3389/feart.2022.940799.
[22]DAS, N., BHUYAN, B., PANDEY, P., 2022, Correlation of soil microbiome with crude oil contamination drives detection of hydrocarbon degrading genes which are independent to quantity and type of contaminants. Environmental Research, 215, 114185 https://doi.org/10.1016/j.envres.2022.114185.
[23]DAVIS, J. B., 1967, Petroleum microbiology: Elsevier Publishing Company, p. 197–245. 604 pp.
[24]DAY, J. W., CLARK, H. C., CHANG, C., HUNTER, R., & NORMAN, C. R., 2020. Life Cycle of Oil and Gas Fields in the Mississippi River Delta: A Review. Water, 12(5), 1492. https://doi.org/10.3390/w12051492.
[25]DE ALEMAR BARBERES, G., 2018, unconventional methods for unconventional plays surface geochemical prospecting for hydrocarbon exploration at South Portuguese Zone. Ph.D. Thesis in Geology – Geological Resources and Environment, FCTUC (Faculdade De Ciencias E technologia) Universidade de Coimbra, 283p.
[26]DECELLES, P. G. & GILES, K. N., 1996. Foreland basin systems. Basin Research, 8, 105–125.
[27]DELGADO-RODRÍGUEZ, O., FLORES-HERNÁNDEZ, D., AMEZCUA-ALLIERI, M.A., ROSAS-MOLINA, A., MARÍN-CÓRDOVA, S., SHEVNIN, V., 2014, Joint interpretation of geoelectrical and volatile organic compounds data: a case study in a hydrocarbons contaminated urban site. Geofísica Internacional, 53 (2): 183-198. https://doi.org/10.1016/S0016-7169(14)71499-0.
[28]DEGOYLER, E., 1940. Future position of petroleum geology in the oil industry. Bull. Am. Assoc. Pet. Geol., 24: 1389--1399.
[29]DING, L., WU, Y., LIU, X., LIU, F., and MEI, H., 2017, Application of microbial geochemical exploration technology in identifying hydrocarbon potential of stratigraphic traps in Junggar Basin, China. AIMS Geosciences, 3 (4): 576-589. DOI: 10.3934/geosci.2017.4.576.
[30]DONOVAN, T. J., ROBERTS, A.A., and DALZIEL, M.C., 1981, Epigenetic zoning in surface and near-surface rocks resulting from seepage-induced redox gradients, Velma oil field, Oklahoma: a synopsis: Oklahoma City Geological Society Shale Shaker, 32(3), 1–7.
[31]DUCHSCHERER JR, W., 1982. Geochemical exploration for hydrocarbons—No new tricks, but an old dog. AAPG Bulletin, 66(2), pp.243-243.
[32]DUCHSCHERER, W. JR., 1980. Geochemical methods of prospecting for hydrocarbons. Oil Gas J., 1, 194-208. [33]DUNN, C.E., HAIDL, F.M., YEAGER, J.R., DORVAL, D., LARSON, B., 1998. Surface geochemical patterns derived from selective leaching of soils over a deep Ordovician oil pool Bromehead, southeastern Saskatchewan. In CHRISTOPHER, J.E., GILBOY, C.F., PATTERSON, D.F, BEND, S. L. (Eds.), Eighth International Williston Basin Symposium: Saskatchewan Geological Society Publication 13, pp. 254 – 265.
[34]GARAIN, S., MITRA, D. & DAS, P., 2019, Detection of hydrocarbon microseepage-induced anomalies by spectral enhancements of Landsat 7 ETM+ images in part of Assam–Arakan Fold Belt, India. J Petrol Explor Prod Technol 9, 2573–2582 (2019). https://doi.org/10.1007/s13202-019-00747-w.
[35]GARAIN, S., MITRA, D., & DAS, P., 2021. Mapping hydrocarbon microseepage prospect areas by integrated studies of ASTER processing, geochemistry and geophysical surveys in Assam-Arakan Fold Belt, NE India. International Journal of Applied Earth Observation and Geoinformation, 102, 102432. doi:10.1016/j.jag.2021.102432.
[36]Ghosh, S., Adsul, T. and Varma, A.K., 2023. Organic matter and mineralogical acumens in CO2 sequestration. Green Sustainable Process for Chemical and Environmental Engineering and Science, pp.561-594.
[37]GOLDMAN, E., and GREEN, L.H., 2008, Practical handbook of microbiology, Second Edition (Google eBook) (2nd edition). USA: CRC Press, Taylor and Francis Group. p. 864.
[38]HARBERT, W., JONES, V. T., IZZO, J., & ANDERSON, T. H., 2006, Analysis of light hydrocarbons in soil gases, Lost River region, West Virginia: Relation to stratigraphy and geological structures. AAPG Bulletin, 90(5), 715–734. http/doi:10.1306/10170505030.
[39] Heuser, E., Becker, K., Idelevich, E. A., 2023, Evaluation of an Automated System for the Counting of Microbial Colonies. Microbiology Spectrum. 11 (4): e00673-23. doi:10.1128/spectrum.00673-23.
[40]HORVITZ, L., 1939. On geochemical prospecting. Geophysics, 4: 210--225.
[41]HORVITZ, L., 1954. Near surface hydrocarbons and petroleum accumulation at depth. Min. Eng., 1205-1209.#3 [42]HORVITZ, L., 1959. Geochemical prospecting for petroleum. 20th lnt. Geol. Congr., Symposium de ExploraeiSn Geoquimrca, 2: 303--319.
[43]HORVITZ, L., 1969. Hydrocarbon geochemical prospecting after 30 years. In: W.B. Heroy (Editor), Unconventional Methods in Exploration for Petroleum and Natural Gas. Southern Methodist University Press, Dallas, Texas, pp. 205--215.
[44]HORVITZ, L., 1972. Vegetation and geochemical prospecting for petroleum. Bull. Am.Aasoc. Pet. Geol., 56: 925--940.
[45]HOSSEINI, A., SABERI, M.H. & ZARENEZHAD, B., 2022, Significance of petroleum seepages in hydrocarbon exploration-case study of Khourian Desert, Central Iran. J Petrol Explor Prod Technol 12, 1649–1663. https://doi.org/10.1007/s13202-021-01440-7.
[46]HOSSEINPOUR, M., 2020. Relationship between hydrocarbon micro-seepages and structures by detection of altered minerals using ASTER remote sensing data in the West of Coastal Fars, Zagros, Iran. Arabian Journal of Geosciences, 13(13). http/doi:10.1007/s12517-020-05568-4.
[47]JIA, W., CHENG, L., TAN, Q., LIU, Y., DOU, J., YANG, K., YANG, Q., WANG, S., LI, J., NIU, G., ZHENG, L., and DING, A., 2023, Response of the soil microbial community to petroleum hydrocarbon stress shows a threshold effect: research on aged realistic contaminated fields. Front. Microbiol. 14:1188229. doi: 10.3389/fmicb.2023.1188229.
[48]JONES, V.T., and DROZD, R.J., 1983. Prediction of oil or gas potential by near-surface geochemistry. Am. Assoc. Pet. Geol. Bull. 67, 932e952.#3 [49]JONES, V.T., MATTHEWS, M.D., RICHERS, D.M., 2000. Light hydrocarbons for petroleum and gas prospecting. In: HALE, M. (Ed.), Handbook of exploration geochemistry, vol. 7. Elsevier Science Publishers, pp. 133-212. http/doi:10.1016/s0168-6275 (00)80029-x.
[50]KARIM, M.F., 1964. Some geochemical methods of prospecting and exploration for oil and gas. Ph.D. Thesis, University of Southern California, University Microfilms Inc.
[51]KARTSEV, А. А., TABASARANSKIY, Z. А., SUBBOTA, M. I., AND MOGILEVSKIY, G.A., 1954, Geochemical methods of prospecting and exploration of oil and gas fields edition of mineral resourses and fuel literature (Мoscow) p 430.
[52]KEBEDE, G., TAFESE, T., ABDA, E.M., KAMARAJ, M., and ASSEFA, F., 2021, Factors influencing the bacterial bioremediation of hydrocarbon contaminants in the Soil: Mechanisms and impacts. Hindawi Journal of Chemistry 2021, Article ID 9823362, 17 pages https://doi.org/10.1155/2021/9823362.
[53]KENDALL, J., VERGÉS, J., KOSHNAW, R., & LOUTERBACH, M., 2019, Petroleum tectonic comparison of fold-thrust belts: the Sevier of the western US, the Pyrenees of Spain, the Zagros of Iraq and Iran, and the Beni Sub Andean of Bolivia. Geological Society, London, Special Publications, SP490–2018–102. http/doi:10.1144/sp490-2018-102.
[54]KENNICUTT, M.C., 2017. Oil and Gas Seeps in the Gulf of Mexico. In: WARD, C. (Eds) Habitats and biota of the Gulf of Mexico: Before the deepwater horizon oil spill. Springer, New York, NY. https://doi.org/10.1007/978-1-4939-3447-8_5.
[55]KLUSMAN, R.W., and SAEED, M.A., 1996, Comparison of Light Hydrocarbon Microseepage Mechanisms. Doi: https://doi.org/10.1306/M66606C12. In: Hydrocarbon Migration and Its Near-Surface Expression, SCHUMACHER, D., AND ABRAMS, M.A., (Eds). American Association of Petroleum Geologists. 66, 157-168.
[56]KROEPELIN, H., 1975. Geochemical prospecting. Proc. 7th World Petroleum Congress, 1B: 37--57.
[57]LAUBMEYER, G., 1933. A new geophysical prospecting method, especially for deposits of hydrocarbons. Petroleum, 29: 1-4.
[58]LINK, W.K., 1952. Significance of oil and gas seeps in world oil exploration. Bull. Am.Assoc. Pet. Geol., 36 (8): 1505-1540.
[59]MACGREGOR, D.S., 1993, Relationships between seepage, tectonics and subsurface petroleum reserves. Mar Pet Geol 10(6):606–619.
[60]MAGOON, L. B. & DOW, W. G., 1994. The petroleum system. In: Magoon, L. B. & Dow, W. G. (eds) The Petroleum System-From Source to Trap. American Association of Petroleum Geologists Memoir, 60, 3-24.
[61]MARTÍNEZ-GÓMEZ, H.M., and JARAMILLO J.M.M., 2017, Magnetic and radiometric signatures in soils above hydrocarbon accumulations, Toqui-Toqui and Mana fields, Tolima, Colombia. Adapted from extended abstract based on oral presentation given at AAPG International Conference and Exhibition, Barcelona Spain, April 3-6, 2016.
[62] MATTHEWS, M. D., 1996, Importance of sampling design and density in target recognition, in D. Schumacher and M. A. Abrams, eds., Hydrocarbon Migration and Its Near-Surface Expression: AAPG Memoir 66, p. 243–253.
[63]MIQUELETTO, P.B., ANDREOTE, F.D., DIAS, A.C.F., FERREIRA, J.C., DOS SANTOS, NETO, E.V., DE OLIVEIRA, V.M., 2011, Cultivation-independent methodsapplied to the microbial prospection of oil and gas in soil from asedimentary basin in Brazil. AMB Express 1(1):1–16. https:// doi.org/ 10. 1186/ 2191- 0855-1- 35.
[64]MORSE, J.G., and ZINKE, R., 1995, The origin of radiometric anomalies in petroleum basins – A proposed mechanism. Oil & Gas Journal, 36-38.
[65]MOTOJIMA, K., 1975, Geochemical prospecting for petroleum and natural gas deposits. Reg. Min. Res. Dev. Cent., Advis. Text No. 9, March.
[66]OEHLER, D.Z., and STERNBERG, B.K., 1984, Seepage-induced anomalies, "false" anomalies, and implications for electrical prospecting. AAPG Bulletin, 68, 1121-1145.
[67] OGISO-TANAKA, E., SHIMADA, D., OGAWA, A., ISHIYAMA, G., OKUMURA, K.I., HOSAKA, K., ISHII, C., NAM, K.-O., HOSHINO, M., NOMURA, S., KAKIZOE, S., NAKAMURA, Y., NISHIUMI, I., ITO, M. A., KITAYAMA, T., TANAKA, N., HOSOYA, T., & JINBO, U., 2025, DNA Specimen Preservation Using DESS and DNA Extraction in Museum Collections. Biology, 14(6): 730. https://doi.org/10.3390/biology14060730.
[68]PHILP, R. P., & CRISP, P. T., 1982, Surface geochemical methods used for oil and gas prospecting- a review. Journal of Geochemical Exploration, 17(1), 1–34. http/doi:10.1016/0375-6742 (82)90017-6.
[69]PIRSON, S.J., 1940. Critical survey of recent developments in geochemical prospecting. Bull. Am. Assoc. Pet. Geol., 24: 1464-1474.
[70]PIRSON, S.J., 1969, Geological, geophysical, and geochemical modification of sediments in the environments of oil fields: Southern Methodist University Press, Dallas, Texas, p. 159-186.
[71]PIXLER, B.O., 1969, Formation evaluation by analysis of hydrocarbon ratios. Jour. Petroleum Technology, 21, 665-670.
[72]PRABAHARAN, S., and SUBRAMANI, T., 2016, Identification of hydrocarbon micro-seeps based on mineral alteration in a par of Cauvery basin, South India, using Hyperion data. Indian Journal of Geo Marine Sciences, 45, 1138-1147.
[73]PRICE, L.C., 1986, A critical overview and proposed working model of surface geochemical exploration: Southern Methodist University Press, Dallas, Texas, p. 245-304.
[74]PUTIKOV, O.F., WEN, B., 2000. Geoelectrochemistry and stream dispersion. In: Hale, M. (Ed.), Geochemical remote sensing of the subsurface, Handbook of exploration geochemistry 7. Amsterdam, Elsevier, pp. 17 – 79.
[75]RASHEED, M.A., KALPANA, M.S., PRASANNA, M.V., LAKSHMI, M., MADHAVI, T., TIWARI, D.M., PATIL, D.J., DAYAL, A.M., RAJU, S.V., 2012b, Geomicrobial and light gaseous hydrocarbon anomalies in the near surface soils of Deccan Syneclise Basin, India: implications to hydrocarbon resource potential. J Petrol Sci Eng 84:33–41. https://doi.org/10.1016/j.petrol.2012.01.010 .
[76]RASHEED, M.A., LAKSHMI, M., KALPANA, M.S., PATIL, D.J., DAYAL, A.M., 2017, Recognition of hydrocarbon microseepage using microbial and adsorbed soil gas indicators in the petroliferous region of Krishna–Godavari Basin, India. Curr. Sci., 112(3):560. https://www.jstor.org/ stable/ 24912 439.
[77]RASHEED, M.A., LAKSHMI, M., RAO, P.L.S., PATIL, D.J., DAYAL, A.M., SUDARSHAN, V., 2012a, Relevance of pentane-and hexane-utilizing bacterial indicators for inding hydrocarbon microseepage: a study from Jamnagar Sub-basin, Saurashtra, Gujarat, India. Natural Resour. Res., 21(4):427–441. https:// doi.org/ 10. 1007/ s11053- 012- 9189-x.
[78]RASHEED, M.A., LAKSHMI, M., SRINU, D., DAYAL, A.M., 2011, Bacteria as indicators for inding oil and gas reservoirs: a case study of the Bikaner-Nagaur Basin, Rajasthan, India. Petrol. Sci., 8(3):264–268. https:// doi.org/ 10. 1007/ s12182- 011- 0143-z.
[79]RASHEED, M.A., PRASANNA, M.V., KUMAR, T.S., PATIL, D.J., DAYAL, A.M., 2008, Geo-microbial prospecting method for hydrocarbon exploration in Vengannapalli village, Cuddapah Basin, India. Curr. Sci., 361–366 https:// www.jstor.org/ stable/ 24102 760.
[80]RASHEED, M.A., PRASANNA, M.V., LAKSHMI, M., MADHAVI, T., KALPANA, M.S., PATIL, D.J., DAYAL, A.M., 2012c. Geo-microbial prospecting studies of surface sediments from petroliferous region of the Mehsana Block, North Cambay Basin. J Geol Soc India 80(2):267–275. https:// doi.org/ 10. 1007/ s12594- 012- 0137-5.
[81] RASHEED, M.A., SRINIVASA RAO, P.L., ANNAPURNA, B., HASAN, S.Z., 2015, Implication of Soil Gas Method for Prospecting of Hydrocarbon Microseepage. International Journal of Petroleum and Petrochemical Engineering (IJPPE), 1 (1): 31-41.
[82]RICHERS, D.M., JONES, V.T., MATTHEWS, M.D., MACIOLEK, J., PIRKLE, R.J., SIDLE, W.C., 1986, The 1983 Landsat soil-gas geochemical survey of Patrick Draw area, Sweetwater County, Wyoming. AAPG Bull 70(7): 869–887.
[83]ROSAIRE, E.E., 1940, Symposium on geochemical exploration. Geochemical prospecting for petroleum. Bull. Am. Assoc. Pet. Geol., 24: 1400-1433.
[84]ROURE, F. & SASSI, W. 1995, Kinematics of deformation and petroleum system appraisal in Neogene foreland fold-and-thrust belts. Petroleum Geoscience, 1, 253-269. DOI: 10.1144/petgeo.1.3.253.
[85]SAATSAZ, M., and REZAEI, A., 2023, The technology, management, and culture of water in ancient Iran from prehistoric times to the Islamic Golden Age. Humanities and Social Sciences Communications 10(1). DOI: 10.1057/s41599-023-01617-x.
[86]SADEGHIZADEH, Z., MOJTAHEDZADEH, S.H., ANSARI, A.H., MORSHEDI, A.H., 2022, Investigation of geochemical anomalies associated with oilfields using matching magnetometric data and satellite images, case study: Moghan plain. Advanced Applied geology, 12 (3), 468-488. DOI: 10.22055/aag.2021.33089.2109.
[87]SATISH KUMAR, T., DAYAL, A. M., & SUDARSHAN, V., 2014. Surface geochemical data evaluation and integration with geophysical observations for hydrocarbon prospecting, Tapti graben, Deccan Syneclise, India. Geoscience Frontiers, 5(3), 419–428. doi:10.1016/j.gsf.2013.08.003.
[88]SAUNDERS, D.F., BURSON, K.R., BROWN, J.J., THOMPSON, C.K., 1993. Combined geological and surface geochemical mathods discovered Agaritta and Brady Creek fields, Concho Country, Texas. AAPG Bull. 77, 1219-1240.
[89]SCHUMACHER, D, 1996, Hydrocarbon-induced alteration of soils and sediments, in: SCHUMACHER, D., and ABRAMS, M.A., (Eds.), Hydrocarbon migration and its near surface expression: AAPG Memoir 66, 71–89.
[90]SCHUMACHER, D., D. C. HITZMAN, J. TUCKER, AND B. ROUNDTREE, 1997, Applying high-resolution surface geochemistry to assess reservoir compartmentalization and monitor hydrocarbon drainage, in R. J. Kruizenga, and M. W. Downey, eds., Applications of Emerging Technologies: Unconventional Methods in Exploration for Oil and Gas V: Dallas, Texas, Southern Methodist Univ. Press, p. 309–322.
[91]SCHUMACHER, D., 2017, Surface geochemical exploration after 100 years: Lessons learned and what more must be done. Adapted from poster presentation given at AAPG 2017 Annual Convention and Exhibition, Houston, Texas, United States, April 2-5, 2017.
[92]SCHUMACHER, D., and ABRAMS, M.A., (Eds.), 1996, Hydrocarbon Migration and Its Near-Surface Expression: AAPG Memoir 66, 445 p.
[93]SECHMAN, H., 2012. Detailed compositional analysis of hydrocarbons in soil gases above multi-horizon petroleum deposits - a case study from western Poland. APPL. GEOCHEM. 27, 2130-2147.
[94]SECHMAN, H., DZIENIEWICZ, M., LISZKA, B., 2012. Soil gas composition above gas deposits and perspective structures of the Carpathian Foredeep, SE Poland. Appl. Geochem. 27 (1), 197-210.
[95]Sechman, H., Guzy, P., Kaszuba, P., Wojas, A., Machowski, G., Twaróg, A., & Maślanka, A., 2020,. Direct and indirect surface geochemical methods in petroleum exploration: a case study from eastern part of the Polish Outer Carpathians. Int J Earth Sci (Geol Rundsch) 109, 1853–1867. https://doi.org/10.1007/s00531-020-01876-y.
[96]SEVERNE, B. C., LANGFORD, G.D., and FULLAGAR, P.K., 1991, Surface geochemical exploration in Australia: case histories from the Eromanga and Canning Basins. APGE Bulleting, 7, 88-115.
[97]SKOLOV, V.A., 1959, Geochemical methods of prospecting for oil and gas deposits. IZD. Akad.Nauk SSR. Moscow.
[98]SOBOLEV, I. S., BREDIKHIN, N. P., BRATEC, T., FALK, A. Y., TOLKACHEV, O. S., RIKHVANOV, L. P., & TISHIN, P. A., 2018. Chemical diagenesis in near-surface zone above oil fields in geochemical exploration. Applied Geochemistry, 95, 33–44. doi:10.1016/j.apgeochem.2018.05.0.
[99]SOKOLOV, V, A., GEODEKYAN, A.A., GRIGORYEV, G.G., KREMS, A.YA., STROGANOV, V.A., ZORKIN, L.M., ZEIDDSON, M.I., and VAINBAUM, S.JA., 1970. The new methods of gas surveys, gas investigations of wells and some practical results. Can. Inst. Min. Metall., 11: 538--543.
[100]SOKOLOV, V.A., 1933. New prospecting method for petroleum and gas. Technika, February Bull. NGRI No. 1.
[101]SOKOLOV, V.A., ALEXEYEV, F.A., BARS, E.A., GEODEKYAN, A.A., MOGILEVSKY, G.A., YUROVSKY, Y.M. AND YASENEV, B.P., 1959. Investigations into direct oil detection methods. Proc. 5th World Petroleum Congress. Section 1, 667-687.
[102]TEDESCO, S.A., 1995, Surface geochemistry in petroleum exploration: New York, Chapman and Hall, Inc., 206 p.
[103]TEDESCO, S.A., 2012, Surface geochemistry in petroleum exploration. Springer, Cham.
[104]THRASHER, J., FLEET, A.J., HAY, S.J., HOVLAND, M., and DÜPPENBECKER, S., 1996. Understanding geology as the key to using seepage in exploration: the spectrum of seepage styles. In: D. SCHUMACHER, M.A. ABRAMS (Eds.), Hydrocarbon migration and its near surface effects, 66, AAPG Memoir, 223-242.
[105]TWARÓG, A., STARZEC, K., SECHMAN, H., SCHNABEL, W., 2024, Surface geochemistry as a key to understanding the petroleum system in regions of complex geology - Polish Outer Carpathians. Marine and Petroleum Geology, 170, 107155. https://doi.org/10.1016/j.marpetgeo.2024.107155.
[106]VAN DER MEER, F., VAN DIJK, P., VAN DER WERFF, H., and YANG, H., 2002, Remote sensing and petroleum seepage: a review and case study. Terra Nova, 14 (1), 1-17.
[107]VARJANI, S.J., 2017, Microbial degradation of petroleum hydrocarbon. Biores Technol 223:277–286. https:// doi.org/ 10. 1016/j. biortec2016. 10. 037.
[108]VERBANAC, B., and DUNIA, P., 1982, Hydrocarbon ratios in gas mixtures as indices of reservoir saturation and producing capacity: Geologija I Geofizika, 33, 185-192.
[109]WAGNER, M., WAGNER, M., PISKE, J., and SMIT, R., 2002. Case histories of microbial prospection for oil and gas, onshore and offshore in northwest Europe. Surface exploration case histories: Applications of geochemistry, magnetics, and remote sensing. AAPG Studies in Geology, 48, 453-479. https://doi.org/10.1306/St48794C19.
[110]WALKER, S., KEYSER, H., and DURHAM, D., 2018, Airborne gamma ray surveying in hydrocarbon exploration. GeoConvention, Calgary, Canada, May 7-11, 2018.
[111]WHITTENBURY, R., PHILLIPS, K.C., WILKINSON, J.F., 1970. Enrichment, isolation and some properties of methane-utilizing bacteria. Microbiology 61(2):205–218.https://doi.org/10.1099/00221287-61-2-205.
[112]WILLIAMS, J.C., MOUSSEAU, R.J., and WEISMANN, T.J., 1981, Correlation of well gas analyses with hydrocarbon seep data: American Chem. Soc. National Meeting, Atlanta, GA. March.
[113]YANG, H., MEER, F.V.D., ZHANG, J., KROONENBERG, S.B., 2000, Direct detection of onshore hydrocarbon microseepages by remote sensing techniques. Remote Sens. Rev., 18(1):1–18. https://doi.org/10. 1080/02757250009532381.
[114]YANG, J.L., WANG, M.S., CHENG, A.C., PAN, K.C., LI, C.F., & DENG, S.X., 2008. A simple and rapid method for extracting bacterial DNA from intestinal microflora for ERIC-PCR detection. World Journal of Gastroenterology, 14(18), 2872. doi:10.3748/wjg.14.2872.
[115]YEATES, C., GILLINGS, M. R., DAVISON, A. D., ALTAVILLA, N., & VEAL, D. A., 1998. Methods for microbial DNA extraction from soil for PCR amplification. Biological Procedures Online, 1(1), 40–47. http/doi:10.1251/bpo6 .
[116]YUAN, Z., ZHANG, Y., ZHAO, Q., JIANG, H., LIU, Y., LUO, Z., LI, X., WANG, S., LI, B., PAN, G., 2009. New progress of microbial prospecting of oil and gas in China: Taking the Satellite Oilield in Daqing as anexample. Sci China Ser D Earth Sci., 52(1):152–158. https:// doi.org/ 10. 1007/ s11430- 009- 5016-6.
[117] ZAJIC, E., and SUPPLISSON, B., 1972, Emulsification and degradation of ‘Bunker C’ fuel oilby microorganisms. Biotechnology and Bioengineering, 14: 331-343.
[118]ZHONG, G., ZHAO, J., ZHAO, Z., ZHANG, K., YU, J., SHANG, C., TU, G., & FENG, C., 2024, Acid-extracted hydrocarbon anomalies and significance in the Chaoshan Depression of the Northern South China Sea. Journal of Marine Science and Engineering, 12(6), 909. https://doi.org/10.3390/jmse12060909.
[119]ZHOU, Q., XU, X., XU, H., ZHENG, G., PI, W., JIANG, Y., XU, X., LI, Y., WANG, J., 2020. Surface microbial geochemistry of the Beihanzhuang Oil field, northern Jiangsu, China. J Petrol Sci Eng., 191:107140. https:// doi.org/ 10. 1016/j. petrol. 2020. 107140.
