ارزیابی کارایی جاذب مغناطیسی قابل بازیافت نیکل فریت در حذف آلاینده رنگی از محیط آبی
الموضوعات : تکنولوژی آب و فاضلاب
سیده بهاره عظیمی
1
,
زهرا منصف خوشحساب
2
,
زهرا ایازی
3
1 - گروه ارزیابی و مخاطرات محیط زیست، پژوهشکده محیط زیست و توسعه پایدار، سازمان حفاظت محیط¬زیست، تهران، ایران.
2 - گروه شیمی، دانشگاه پیام نور، قزوین، ایران.
3 - گروه شیمی، دانشکده علوم پایه، دانشگاه شهید مدنی آذربایجان، تبریز، ایران.
الکلمات المفتاحية: تصفیه پساب, فرایند جذب سطحی, نانو ذرات مغناطیسی, نیکل فریت,
ملخص المقالة :
در این پژوهش جاذب مغناطیسی نیکل فریت سنتز و مشخصه‌یابی شده و برای حذف رنگ از محیط آبی به روش جذب سطحی مورد استفاده قرار گرفته است. به این منظور تاثیر پارامترهای مختلف از قبیل غلظت اولیه رنگ، مقدار جاذب، زمان تماس و pH محلول به روش طراحی آزمایش بررسی، مدل و بهینه شده است. همچنین سینتیک فرایند بر اساس معادلات شبه مرتبه اول و شبه مرتبه دوم بررسی شده و تطابق فرایند با الگوهای جذبی لانگمویر و فراندلیچ مورد ارزیابی قرار گرفته است. مشخصه‌یابی جاذب سنتز شده نشان داد که جاذب مغناطیسی به طور متوسط nm 18 است. مدل سازی و بهینه سازی فرایند به روش آماری پاسخ سطح (RSM) در قالب طراحی مرکب مرکزی (CCD) انجام شد و نتایج نشان داد که در شرایط بهینه شامل غلظت اولیه رنگ mg/L 110، زمان تماس min 90، مقدار جاذب g 0/05 و 3 = pH، مقدار جذب تعادلی mg/g 3/76 (معادل 93/2 درصد بازده حذف رنگ) است. بنابراین، با توجه به ساختار رنگ و نوع جاذب مورد استفاده بازده در شرایط اسیدی بهتر است. بررسی سینتیک و همدمای جذب نشان داد که فرایند از سینتیک شبه مرتبه دوم و همدمای لانگمویر تبعیت کرده و بر اساس معادله لانگمویر مقدار حداکثر ظرفیت جذب رنگ mg/g 21/1 است. با توجه به مغناطیسی بودن جاذب مورد استفاده، در پایان فرایند میتوان جاذب را از محیط به راحتی و با کمترین هزینه جدا کرد.
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